Which ionospheric region is the most absorbent of signals below 10 MHz during daylight hours?
Why The D region is the lowest ionized layer, about 60 to 90 km up, where air density and therefore electron-neutral collision rates are highest. Electrons set in motion by a passing wave collide with neutral molecules and lose that energy as heat instead of re-radiating it, so the wave is attenuated rather than refracted. This absorption rises sharply as frequency falls (roughly as 1/f squared), which is why 160, 80 and 40 meters are short-range in daylight but open up at night when the D region quickly disappears.
Watch out The E and F regions are the ones that actually refract HF signals back to Earth; the F2 region is the main daytime long-haul reflector, not an absorber.
D is for Daytime Deadener: lowest region, kills the low bands until sunset.