Why is long-distance communication on the 40-, 60-, 80-, and 160-meter bands more difficult during the day?
Why The D region is the lowest ionospheric layer (about 50-90 km) and it only exists while the sun is up, because it requires constant solar ionization and its dense air lets ions recombine within minutes after sunset. Rather than refracting signals back to Earth, the D region absorbs them, and that absorption gets much stronger as frequency goes down (roughly proportional to 1/f squared). So the low bands, 160, 80, 60 and 40 meters, lose their energy on the way up during the day, and only come alive for DX after dark when the D region disappears.
Watch out The F region is what actually refracts HF signals back to Earth for long-haul work; it does not absorb the low bands, and daytime is when it is strongest, splitting into F1 and F2.
D is for Daytime and Death of the low bands. Lower frequency, more D-region absorption.